| Termijn | Thuis | Uitteam | Uitslag |
|---|---|---|---|
| 1-6-13 17:00 | Real Madrid | CA Osasuna | 4:2 |
| 1-6-13 19:00 | FC Barcelona | FC Malaga | 4:1 |
| 1-6-13 21:00 | UD Levante | Real Betis Sevilla | 1:1 |
| 1-6-13 21:00 | Deportivo La Coruna | Real Sociedad | 0:1 |
| 1-6-13 21:00 | Rayo Vallecano | Athletic Bilbao | 2:2 |
| 1-6-13 21:00 | RCD Mallorca | Real Valladolid | 4:2 |
| 1-6-13 21:00 | Celta Vigo | Espanyol Barcelona | 1:0 |
| 1-6-13 21:00 | Real Saragossa | Atletico Madrid | 1:3 |
| 1-6-13 21:00 | FC Granada | FC Getafe | 2:0 |
| 1-6-13 21:00 | FC Sevilla | FC Valencia | 4:3 |