| Termijn | Thuis | Uitteam | Uitslag |
|---|---|---|---|
| 19-7-20 17:00 | Deportivo Alaves | FC Barcelona | 0:5 |
| 19-7-20 18:30 | Real Valladolid | Real Betis Sevilla | 2:0 |
| 19-7-20 18:30 | FC Villarreal | SD Eibar | 4:0 |
| 19-7-20 21:00 | Espanyol Barcelona | Celta Vigo | 0:0 |
| 19-7-20 21:00 | FC Sevilla | FC Valencia | 1:0 |
| 19-7-20 21:00 | CD Leganes | Real Madrid | 2:2 |
| 19-7-20 21:00 | FC Granada | Athletic Bilbao | 4:0 |
| 19-7-20 21:00 | Atletico Madrid | Real Sociedad | 1:1 |
| 19-7-20 21:00 | CA Osasuna | RCD Mallorca | 2:2 |
| 19-7-20 21:00 | UD Levante | FC Getafe | 1:0 |